I've had no personal experience with the UC33e, but I've got an old UC16 from a few years ago, and it's simple and reliable.
My only criticism with it is the complicated scene mapping; but the upside to the UC33e is that a piece of software that deals with scene/control mapping is bundled. For what it was (a 16 rotary, USB controller) it did the job well.
If you've got a few more bucks to spend, then I'd probably go for the Zero SL, because it's got trigger pads, and a much nicer control surface; albeit larger than the UC33e (and with 8 less rotaries), but definitely worth that extra £45!
Edit: Another criticism with the UC controller... the controller resolution wasn't that high. Probably something like 127 steps. With the Zero SL, it'd probably be much, much higher.
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MacBook Pro: NI Audio Kontrol 1; Logic Studio 8; Ableton Live; Sibelius 5; NI Komplete 5; various other plugs. Fostex PM1 MkII; Yamaha AN1x; Novation 25SL MkII; Audio Technica ATH-M50; Roland SH32
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